The Sinister Six (Wikipedia)

The Sinister Six are a group of supervillains in the Marvel Comics universe, drawn from Spider-Man's rogues gallery. The original incarnation of the group was organized by Doctor Octopus, and first appeared in The Amazing Spider-Man Annual #1 (January 1964).^[1]
After suffering three defeats in a row from the wall-crawler, Doctor Octopus realized that he would require assistance from Spider-Man's other enemies in order to defeat him. After his recent defeat followed by the police successfully removing the tentacle pack, Doctor Octopus mentally controls his tentacles to come to him and he escapes from jail. Afterwards, he contacted every known supervillain that had crossed paths with Spider-Man, but only Vulture, Electro, Kraven the Hunter, Mysterio, and Sandman responded. Knowing he'd never be able to keep the team together for long, Doctor Octopus quickly formulated a battle plan in which each individual member of the Sinister Six would battle Spider-Man in a carefully chosen location, giving each of them personal glory and Spider-Man an early death.

• The Sinister Six will be hinted in the upcoming film The Amazing Spider-Man 2 to appear in future installments. Actors Chris Cooper and Paul Giamatti have both revealed that they would return as Norman Osborn and Rhino for The Amazing Spider-Man 3. In the teaser trailer of The Amazing Spider-Man 2, Doctor Octopus's arms and Vulture's wings, along with the Green Goblin on his glider, can be seen.
• In December 2013, Sony announced two spinoffs of the Amazing Spider-Man series, which include the Sinister Six and Venom, with Drew Goddard attached to write the film with an eye to direct.^[35]

Check out this video of the Spectacular Spider-man vs the Sinister six. I do not own this!!!